Bridging Heterogeneous and Homogeneous Catalysis: Concepts, Strategies, and Applications
Can Li · Yan Liu
2014年4月 · John Wiley & Sons
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656
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There are two main disciplines in catalysis research -- homogeneous and heterogeneous catalysis. This is due to the fact that the catalyst is either in the same phase (homogeneous catalysis) as the reaction being catalyzed or in a different phase (heterogeneous catalysis). Over the past decade, various approaches have been implemented to combine the advantages of homogeneous catalysis (efficiency, selectivity) with those of heterogeneous catalysis (stability, recovery) by the heterogenization of homogeneous catalysts or by carrying out homogeneous reactions under heterogeneous conditions.
This unique handbook fills the gap in the market for an up-to-date work that links both homogeneous catalysis applied to organic reactions and catalytic reactions on surfaces of heterogeneous catalysts. As such, it highlights structural analogies and shows mechanistic parallels between the two, while additionally presenting kinetic analysis methods and models that either work for both homogeneous and heterogeneous catalysis.
Chapters cover asymmetric, emulsion, phase-transfer, supported homogeneous, and organocatalysis, as well as in nanoreactors and for specific applications, catalytic reactions in ionic liquids, fluorous and supercritical solvents and in water. Finally, the text includes computational methods for investigating structure-reactivity relations.
With its wealth of information, this invaluable reference provides academic and industrial chemists with novel concepts for innovative catalysis research.
This unique handbook fills the gap in the market for an up-to-date work that links both homogeneous catalysis applied to organic reactions and catalytic reactions on surfaces of heterogeneous catalysts. As such, it highlights structural analogies and shows mechanistic parallels between the two, while additionally presenting kinetic analysis methods and models that either work for both homogeneous and heterogeneous catalysis.
Chapters cover asymmetric, emulsion, phase-transfer, supported homogeneous, and organocatalysis, as well as in nanoreactors and for specific applications, catalytic reactions in ionic liquids, fluorous and supercritical solvents and in water. Finally, the text includes computational methods for investigating structure-reactivity relations.
With its wealth of information, this invaluable reference provides academic and industrial chemists with novel concepts for innovative catalysis research.
作者简介
Can Li received his PhD degree from the Dalian Institute of Chemical Physics (China) in 1988, was promoted to full professor in 1993, and was elected as a member of the Chinese Academy of Sciences in 2003. He was appointed director of the State Key Laboratory of Catalysis at the Dalian Institute of Chemical Physics in 1998 and elected to the President of the International Association of Catalysis Societies in 2008. He is a member of the editorial board of more than 15 academic journals and has published more than 400 peer-reviewed papers, authorized 40 patents and delivered more than 60 invited and plenary lectures at national and international conferences. Under his supervision, more than 60 graduate students have obtained their PhD degrees. Among the prestigious awards he received are the International Catalysis Award, the National Award for Outstanding Young Scientists in China, and the HoLeungHoLee Prize. His research interests are physical chemistry, catalysis, environmental catalysis, chiral catalysis, in-situ characterization, resonance and time-resolved spectroscopy, and solar energy utilization (photocatalysis, photoelectrocatalysis and photovoltaic).
Yan Liu studied chemistry at Lanzhou University (China) and then moved to the State Key Laboratory of Organometallic Chemistry at the Shanghai Institute of Organic Chemistry to obtain his PhD degree under the supervision of Prof. Kuiling Ding in 2006. After three years of postdoctoral studies with Prof. Li Deng, Brandeis University (USA), he joined Prof. Can Li?s group at the State Key Laboratory of Catalysis at the Dalian Institute of Chemical Physics in 2010 as associate professor and was promoted to full professor in 2013.
Yan Liu studied chemistry at Lanzhou University (China) and then moved to the State Key Laboratory of Organometallic Chemistry at the Shanghai Institute of Organic Chemistry to obtain his PhD degree under the supervision of Prof. Kuiling Ding in 2006. After three years of postdoctoral studies with Prof. Li Deng, Brandeis University (USA), he joined Prof. Can Li?s group at the State Key Laboratory of Catalysis at the Dalian Institute of Chemical Physics in 2010 as associate professor and was promoted to full professor in 2013.
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